Assuming you have one btrfs partition used as root (/) and you want to create RAID 1 using another partition
Check btrfs filesystem
btrfs filesystem show
Add another partition to root with force
btrfs device add /dev/sdb1 / -f
Check filesystem
btrfs filesystem show
Result is something like
Label: none uuid: 2601731d-934b-4c18-90fa-aa9cc61ced98
Total devices 2 FS bytes used 6.47GiB
devid 1 size 119.24GiB used 10.02GiB path /dev/sda2
devid 2 size 119.24GiB used 0.00B path /dev/sdb1
Start RAID1 in root (/)
btrfs balance start -dconvert=raid1 -mconvert=raid1 /
Check file system usage
btrfs filesystem df /
When balancing is going on there is warning
WARNING: Multiple block group profiles detected, see 'man btrfs(5)'
WARNING: Data: single, raid1